How to Print Labels From Excel? | Steps to Print Labels from Excel - EDUCBA Step #3 - Set up Labels in a Blank Word Document In a blank word document, Go to > Mailings, select > Start Mail Merge, select > Labels. A new pane called Label Options will open up. Under that, select Label vendors as Avery US Letter, Product number as 5160 Address Labels. Then, click OK. See the screenshot below.